![]() PROCESS FOR MANUFACTURING A BOXING CONTAINER BASED ON BLOWING
专利摘要:
A method of manufacturing a container (2) from a blank (3) in a mold (5) provided with a movable insert (9), said method comprising the following steps: - pre-blowing; - blowing; - boxing; and the following operations: measuring in real time and storing the pressure prevailing in the blank (3); measuring in real time and memorizing the position of the insert (9); detecting and storing an instant tS2 marking the actual start of the blowing phase and an instant tB2 marking the actual start of the displacement of the insert (9); calculate T1 = tS2 - tB2; comparing T1 with a non-zero predetermined reference value T1, while T1 is different from T1 ref, staggering the initiation of the boxing phase. 公开号:FR3029133A1 申请号:FR1461575 申请日:2014-11-27 公开日:2016-06-03 发明作者:Pierrick Protais;Franck Santais;Mikael Derrien 申请人:Sidel Participations SAS; IPC主号:
专利说明:
[0001] The invention relates to the manufacture of containers by forming plastic blanks such as polyethylene terephthalate (PET). A conventional technique for manufacturing containers is blowing (possibly doubled by stretching). This technique consists in introducing the preform (that is to say a preform or an intermediate container having undergone a preforming operation), previously heated to a temperature above the glass transition temperature of the material (about 80 ° C. in the case of PET), in a mold provided with a wall defining a cavity in the impression of the container, and in injecting into the blank, through an opening of which it is provided at its neck, a fluid, such as as a pressurized gas (usually air) to press the material against the wall of the mold. More specifically, the forming generally comprises two consecutive phases: a pre-blowing phase in which is injected into the blank a fluid at a pre-blowing pressure, and a blowing phase in which is injected into the blank a fluid to a blowing pressure higher than the pre-blowing pressure. In conventional processes, where air is used to carry out the forming, the pre-blowing pressure is between 5 and 10 bar, and the blowing pressure between 20 and 40 bar. For certain applications, it is necessary to form cavities on the container, in particular for aesthetic purposes (eg creation of curves), functional (making a handle for gripping the container) or structural (eg production). side panels or bottom that has undergone additional stretching, to absorb the deformation of the container during a hot filling). [0002] When such a reserve reaches a certain depth, the container can not be formed in an ordinary mold because, despite the high blowing pressure, it is insufficient to perfectly apply the material against the relief of the mold intended to form the reserve, especially in areas facing away from the neck of the container from which the blowing bubble develops. Also, molds with mobile inserts initially retracted in the wall of the mold and deployed during forming to push the wall of the container are usually used, as illustrated in the European patent application EP 1 922 256 or the corresponding US patent application US 2009/139996 (Sidel). [0003] This technique, commonly known as "boxing", is particularly used for forming containers with an integrated handle, or a bottom that has undergone additional stretching and intended to absorb the deformation of the container during a hot filling, cf. European Patent Application EP 2 173 637 (Sidel). [0004] The boxing technique is complex because, depending on the shape and the depth of the reserves to be made, the embossing carried out by the insert can lead to a thinning of the material, or even a local rupture of the wall of the container which makes it unusable. This is why the adjustment of machines dedicated to boxing is delicate; it is generally entrusted to experienced operators whose turn allows to make conforming containers in the judgment. But it is usual that the setting parameters (including pressure, flow rate and speed of movement of the insert), initially correct, undergo in the course of manufacturing uncontrolled drifts that affect the quality of the containers. Since experienced operators are not always available to correct the settings, it is sometimes necessary to stop the production line to avoid the accumulation of non-compliant containers. In addition, it has been determined that the quality of the containers - particularly in terms of mechanical performance - derives from a precise adjustment of the boxing phase with respect to the pre-blowing and blowing phases. In particular, it has been determined that it is advantageous to initiate boxing before blowing, cf. European Patent Application EP 2 709 821 (Sidel). [0005] However, tests have shown that this criterion alone can be insufficient to guarantee a good container quality. The invention therefore aims to further improve manufacturing techniques with boxing, to improve the quality of the containers produced. [0006] For this purpose, there is provided a method of manufacturing a container from a plastic blank, within a mold having a wall defining a cavity in the cavity of the container, and a movable insert relative to the wall between a retracted position and an extended position, this method comprising, after an operation for introducing the blank into the mold: a pre-blowing phase comprising injecting into the blank a fluid at a pre-blowing pressure; a blowing phase, consecutive to the pre-blowing phase and comprising injecting into the blank a fluid at a blowing pressure greater than the pre-blowing pressure; a boxing phase comprising moving the insert from its retracted position to its deployed position; this method further comprising the steps of: measuring in real time the pressure prevailing in the blank; memorizing the values of the measured pressure and their respective times of measurement; - Measure in real time the position of the insert; storing the values of the measured position of the insert and their respective moments of measurement; from the stored values of the pressure in the blank, detecting and storing a moment ts2 marking the actual start of the blowing phase; from the measured position values of the insert, detecting and storing an instant tB2 marking the actual beginning of the displacement of the insert; calculate the interval, denoted Ti, separating tB2 from tS2; comparing the interval Ti with a predetermined non-zero reference tire value, as long as the interval Ti is decreed different from the reference tire value, stagger the initiation of the boxing phase. This process is based on the assumption, formulated following tests carried out on numerous containers, that, to obtain containers produced of high quality and above all constant (in particular, when the insert is a bottom of mold, in terms of performance mechanical the bottom of the container), it is necessary to maintain constant advance (expressed above in terms of interval noted Ti) boxing on blowing (assuming the blowing itself). The automatic correction is performed, when a drift is noted in the advance Ti, from one cycle to another in a first case, or periodically after data has been collected over several cycles in a second case. This correction (which corresponds for example, in the second case, to an average calculated over several cycles) makes it possible to manufacture containers conforming to a high quality standard without, however, having to resort to manual adjustment of the machine. The mentioned offset can consist, as long as the interval Ti is decreed lower than the value Tire of reference, to advance the phase of boxing. In the case where the insert is secured to the rod of a cylinder supplied with pressurized fluid via a controlled opening distributor, the offset of the initiation of the boxing phase consists in shifting the control of opening of the dispenser. [0007] The following additional operations may be provided: from the measured position values of the insert, detecting a time tB3 at which the insert reaches its high position; calculate the interval, denoted T2, separating tB3 from tB2; comparing the interval T2 with a predetermined non-zero reference reference value T2ref; as long as the interval T2 is decreed different from the value T2ref of reference, to modify the speed of displacement of the insert during the phase of boxing. In the case where the insert is secured to the rod of a jack supplied with pressurized fluid, are further provided the operations of: measuring the position of the insert at time ts2 marking the actual start of the blowing phase , check if the position of the insert is between two predetermined values and if T2 is also between two predetermined values, if these two conditions are not jointly satisfied, generate an alert. In addition, in the case where the cylinder is connected to an evacuation via a variable speed drive, it can be provided, if the position of the insert is not between two predetermined values or T2 n is not included between two predetermined values, an operation of modifying the fluid flow rate at the variable speed controller. Alternatively, the following operations can be provided: from the memorized values of the pressure in the blank, detecting and storing an instant ts3 at which the pressure in the blank ceases to increase during the blowing phase; from the measured position values of the insert, detecting a time tB3 at which the insert reaches its high position; calculate the interval, denoted T3, separating ts3 from tB3; comparing the interval T3 with a predetermined non-zero reference reference value T3ref; as long as the interval T3 is decreed different from the value T3ref of reference, to modify the speed of displacement of the insert during the phase of boxing. [0008] In the case where the insert is secured to the rod of a jack supplied with pressurized fluid via a controlled opening distributor and a pressure variator, the change in the speed of movement of the insert may be to act on the pressure variator to change the fluid pressure supplying the cylinder. [0009] In the case where the insert is secured to the rod of a cylinder supplied with pressurized fluid via a controlled opening distributor, the following additional operations can be provided: measuring a response time of the cylinder and / or a distributor response time and, comparing this response time to a predetermined threshold value, when this response time is greater than the reference value, generating an alert. In addition, in the case where the insert is secured to the rod of a cylinder supplied with pressurized fluid via a controlled opening distributor and a pressure variator, the cylinder being further connected to an evacuation via a variable speed drive, may further be provided the operations consisting, if the flow rate at the drive reaches a minimum, respectively a maximum, to control the pressure variator to decrease, respectively increase, the pressure injected into the cylinder. [0010] Other objects and advantages of the invention will emerge in the light of the description of an embodiment, given below with reference to the accompanying drawings in which: FIG. 1 is a schematic sectional view showing a forming unit equipped with a mold in which takes place the forming of a container, shown at the moment of the beginning of the pre-blowing phase; Figure 2 is a view similar to Figure 1, illustrating the end of the pre-blowing phase; Figure 3 is a view similar to Figure 1, illustrating the end of the boxing phase; FIG. 4 is a diagram on which are plotted in parallel, from top to bottom and temporally synchronized: the boxing curve giving the evolution of the position of the insert over time, the pressure curve relating the evolution the pressure prevailing in the container over time, the timing of control of the phases of pre-blowing, blowing and boxing. In Figure 1 is shown a unit 1 for forming a container 2 by stretching blow from a blank 3 of plastic, including PET (polyethylene terephthalate). The blank 3 may be a raw injection preform (as in the example illustrated) or an intermediate container obtained by one or more preliminary forming operations performed on a blank preform. [0011] In practice, the forming unit 1 is mounted, with other similar forming units 1, on a rotating carousel of a forming machine. The forming unit 1 is automatically driven by a control unit 4 comprising at least one controller (for example of the API type - acronym for an industrial PLC) equipped with actuators. The forming unit 1 comprises, in the first place, a mold 5 provided with a wall 6 defining a cavity 7 at the impression of the container 2 to be formed, which extends along a principal axis X and has an opening 8 , and an insert 9 movably mounted in the opening 8 with respect to the wall 6. The insert 9 is provided with an internal surface 10 with the imprint of a reserve to form recessed on the container 2. According to an embodiment illustrated in the drawings, this reserve is a bottom of the container, the additional stretching provided by the mobility of the insert 9 during forming leads to a better structural rigidity due to an increase in the crystallinity of the container. material. In what follows, it is assumed that the insert 9 is a mold bottom. In this case, the opening 8 is made axially in the lower part of the wall 6. In a variant, not shown, the recessed reserve is for example intended to form a handle or accommodate a reported handle. In this case, the insert would be disposed on one side of the wall 6, and the opening would be made radially on this side. The mode of operation of such an insert would be the same as that described below where the insert 9 is a mold bottom. The bottom 9 of the mold is mounted movable with respect to the wall 6 between a retracted (or low) position, illustrated in FIG. 1, in which the bottom 9 of the mold extends backwards with respect to the cavity 7 while being spaced apart. 8, and an extended or raised position, illustrated in FIG. 3, in which the bottom 9 of the mold seals the opening 8, and in which the internal surface closes the cavity 7, thus completing the cavity of the container 2. The "distance" of the mold base is the distance, denoted C, separating its low position from its high position. The mold 5 is for example of the wallet type and comprises two half-molds 5A, 5B hinged around a common hinge and which open to allow, successively, the evacuation of a container 2 formed and the introduction of a blank 3, previously heated in a thermal conditioning machine placed upstream of the forming machine. Each forming unit 1 comprises, secondly, an injection device 11 comprising a nozzle 12 defining an injection chamber 13. The nozzle 12 is mounted directly above the mold 5 while being axially movable relative thereto between a disengaged position in which the nozzle 12 is spaced from the mold to allow both the introduction of a blank 3 into the and evacuating it from a shaped container 2, and a coupled position (illustrated in FIGS. 1 to 3) in which the nozzle 12 is sealingly applied against the mold 5 around the blank 3 to ensure the fluidic communication of the injection chamber 13 with the inside of the blank 3. The injection device 11 further comprises a pre-blowing fluidic circuit 14, which fluidly connects the injection chamber 13 to a source 15 of fluid at a so-called pre-blowing pressure, via a pre-blowing solenoid valve 16 controlled by the control unit 4. In practice, the fluid is a gas, such as air. The pre-blowing pressure is for example between 5 and 10 bar. [0012] The injection device 11 further comprises a fluidic blowing circuit 17, which fluidly connects the injection chamber 13 to a source 18 of fluid at a so-called blowing pressure, greater than the pre-blowing pressure, via a solenoid valve 19 blowing controlled by the control unit 4. In practice, the fluid is air. The blowing pressure is for example between 20 and 40 bar. The injection device 11 comprises, finally, a degassing circuit (not shown) which fluidly connects the injection chamber 13 to the free air, via an air-venting solenoid valve also controlled by the control unit 4. [0013] Each forming unit 1 comprises, in the third place, a drawing unit equipped with a drawing rod 20 which extends along the X axis of the mold 5 and up to a rounded distal end 21 and is mounted movably axially with respect to the mold 5. The rod 20 extends axially through the nozzle 12, sealingly. [0014] The forming unit 1 also comprises a pressure sensor 22 mounted on the nozzle 12 for measuring the pressure in the injection chamber 13, which is identical to that prevailing in the blank 3 and then in the container 2. sensor 22 is connected to the control unit 4 which stores the values at each moment (according to a predetermined period, for example of the order of a few milliseconds). The forming unit 1 comprises, fourthly, an actuator 23 for controlling the position of the bottom 9 of the mold. According to an embodiment illustrated in FIG. 1, this actuator 23 is in the form of a jack provided with a cylindrical jacket 24, a bottom wall 25 and a top wall 26 closing the jacket 24 at each its ends, and a piston 27 slidably mounted in the sleeve 24 between the walls 25, 26. The piston 27 is secured to a rod 28 through the upper wall 26. The bottom 9 of the mold is mounted on the rod 28 at an upper end thereof protruding from the upper wall 26. Fixing the bottom 9 of the mold on the rod 28 can be performed in a conventional manner, typically by screwing. The piston 27 and the rod 28 are integrally movable with respect to the liner 24 between a retracted position, corresponding to the retracted position of the mold base 9 (FIG. 1), and an extended position corresponding to the extended position of the bottom 9 of the mold. mold. [0015] In the example shown, the cylinder 23 is of the double-acting type. The piston 27 defines on the one hand, with the lower wall 25, a primary chamber 29 and, on the other hand, with the upper wall 26, a secondary chamber 30. To control the cylinder 23, the forming unit 1 comprises a primary fluid circuit 31 and a secondary fluid circuit. The primary fluid circuit 31 comprises a primary distributor 33 of the 3/2 type (three orifices, two positions, this type of distributor can be likened to a three-way solenoid valve) controlled by the control unit 4. The primary distributor 33 has a first inlet through which it is connected to a primary source 34 of pressurized fluid (which may be confused with the source 18 of fluid at the blowing pressure) and a second inlet through which it is connected to The primary dispenser 33 further has an outlet through which it is connected to the primary chamber 29 via a primary orifice 36 in the lower wall. According to a preferred embodiment illustrated in FIG. 1, a pressure variator 37 is interposed between the primary source 34 and the first input of the primary distributor 33, and connected to the control unit 4 which controls it. The function of the variator 37 is to vary the pressure 30 in the primary chamber 29, according to a set point imposed by the control unit 4, in particular as a function of the capacity of the container 2 to be formed, and more precisely as a function of the diameter of the 9 mold bottom. The secondary circuit 32 comprises a secondary distributor 38 of the 3/2 type controlled by the control unit 4. The secondary distributor 38 has a first inlet through which it is connected to a secondary source 39 of pressurized fluid (which may be confused with the source 18 of fluid at the blowing pressure and with the primary source 34) and a second input by it is connected to an evacuation 40. The secondary distributor 38 also has an outlet through which it is connected to the secondary chamber, via a secondary orifice 41 formed in the upper wall 26. According to an embodiment illustrated in FIG. 1, the secondary fluidic circuit 32 comprises a variable speed controller (or restrictor) 42 interposed between the secondary distributor 38 and the secondary orifice 41. The function of the variable speed variator 42 is to modulate the flow of fluid injected into the secondary chamber, and thus the speed of movement of the piston 27 (and of the mold base 9 which is integral with it). According to an alternative embodiment, the jack 23 is electric. The forming unit 1 comprises, finally, a sensor 43 of the mold base 9, connected to the control unit 4. The bottom 9 of the mold being integral with the piston 27, the sensor 43 can measure the position thereof. It can be a capacitive sensor, a magnetic sensor, or an optical sensor. The drawing rod 20 being kept in contact with the bottom 9 of the mold (the material of the bottom of the container 2 being sandwiched between them) during the boxing phase, the measurement of the position of the bottom 9 of the mold can be carried out by measuring the position of the rod 20, as described in the French patent application FR 2 998 207 or its international equivalent VVO 2014/080109. The manufacture of a container 2 from a blank 3 (in particular a preform) during a forming cycle firstly comprises a preliminary phase for introducing the blank 3 into the mold 5, driven in a position first. open and then closed thereof, and in the bottom position of the bottom 9 of the mold. Before its introduction into the mold 5, the blank 3 was first heated to a temperature above the glass transition temperature of the material (about 80 ° C in the case of PET) to have a certain malleability. A pre-blowing phase of the blank 3 is then provided, which comprises: the descent of the rod 20, as soon as the rod 20 reaches the bottom of the blank 3, the injection into it of fluid under pressure pre-blowing; for this purpose, the control unit 4 controls the opening of the pre-blowing solenoid valve 16 to put in fluid communication the fluid source 15 at the pre-blowing pressure with the injection chamber 13 (and therefore with the blank 3). It is assumed that the pre-blowing phase is compliant, that is to say that it has no noticeable shift (time or pressure) with respect to a predetermined blowing pattern. The descent speed of the rod 20 is such that it remains in contact with the bottom of the preform constituting the blank 3 until it reaches the bottom 9 of the mold. The pre-blowing causes the swelling of the blank 3 to come into only partial contact with the wall 6 and the bottom 9 of the mold, the pre-blowing pressure not being sufficient to completely press the blank 3 against the wall 6. In other words, the impression is insufficient. This is why, after the pre-blowing phase, there is provided a blow-molding phase of the blank, which comprises injecting the blank 3 into the fluid at the blowing pressure; for this purpose, the control unit 4 controls the closing of the pre-blowing solenoid valve 16 and the opening of the blowing solenoid valve 19 to put in fluid communication the source 18 of fluid at the blowing pressure with the chamber 13 injection (and thus with the blank 3). The closing of the pre-blowing solenoid valve 16 is controlled by the control unit 4 simultaneously with (or with a slight delay on) the opening control of the blowing solenoid valve 19. It is assumed that the blowing phase is compliant, that is to say that it has no significant offset (time or pressure) with respect to a predetermined blowing pattern. As illustrated in the figures, there is further provided a boxing phase which comprises moving the bottom 9 of the mold from its low position to its upper position. In its low position, the primary orifice 36 of the jack 23 is in fluid communication with the discharge 35, and the secondary chamber 30 in fluid communication with the secondary source 39 of fluid under pressure. To move the mold base 9 to its high position, the pilot control unit 4: - the primary distributor 33 for placing the primary orifice 36 of the cylinder 23 in fluid communication with the primary source 34 of fluid; the secondary distributor 38 for placing the secondary orifice 41 in fluid communication with the discharge 40. The piston 27 is then pushed towards its high position under the pressure of the fluid in the primary chamber 29, against the resistant force fluid of the secondary chamber. According to one embodiment, the control unit 4 controls the pressure variator 37 and the variable speed variator 42 for modulating the speed of movement of the piston (and therefore of the mold base 9) and the thrust exerted thereon. The control laws of the pressure variator 37 and the flow variator 42 may be based on the diameter of the mold base 9: it is indeed preferable that the displacement speed (and thus the flow rate) be high when the bottom 9 of the mold The mold is of large diameter, and comparatively smaller when the bottom 9 of the mold is of small diameter. [0016] The boxing phase is initiated with a slight advance on the blowing phase, in particular to avoid the pinching of the material between the bottom 9 of the mold and the opening 8 and especially, as has been found, to form at best the bottom of the container 2 when this advance is correctly set. The boxing makes it possible to perform additional stretching on the bottom of the container 2, favorable to the orientation of the molecules (and therefore to the mechanical rigidity). During the entire forming cycle, the pressure in the blank 3 is measured in real time, and the values of the measured pressure and their respective measurement times are stored by the control unit 4. Likewise, during the forming cycle, the position of the mold base 9 is measured in real time by the sensor 43, and the values of the measured position of the mold base 9 and their respective moments of measurement are stored by the control unit 4. [0017] FIG. 4 shows the curves representing, as a function of time (denoted t): - at the top, the axial position (or height, denoted H) of the bottom 9 of the mold, - in the middle, the pressure (denoted P) prevailing in the blank 3 or in the container 2 during forming; at the bottom, the timing diagrams of the pre-blowing solenoid valve 16 (noted PR), the solenoid blowing solenoid 19 (denoted SO) and the distributors 33, 38 (denoted FDM). The curves are synchronized on the time axis common to them, the vertical dashed lines making it possible to perform a matching of the curves at certain selected moments. As already mentioned, measurements are made at regular intervals. These intervals can be defined by a clock rate provided by the control unit 4, less than or equal to the maximum rate at which the pressure sensor 22 and the position sensor 43 of the mold base can operate. The curves appear continuous in FIG. 4 because the control unit 4 can, by simple interpolation (in particular polynomial), thus construct them from the point measurements provided by the sensors 22, 43. [0018] The opening control of the pre-blowing solenoid valve 16 is given at a time tpi called "pre-blast top start". The pre-blowing solenoid valve 16 is assigned a response time 44, the pressure P prevailing in the container 2 undergoes a rise from a time tp2, referred to as "actual start pre-blowing", such that tp2 = tpi + Similarly , the opening control of the solenoid valve 19 blowing is given at a time ts1 called "top start blowing". The solenoid blower 19 being assigned a response time Ats, the pressure P prevailing in the container 2 undergoes an inflection (sudden growth) from a moment ts2 called "actual blow start" such that ts2 = ts1 + Ats, which marks the actual beginning of the blowing phase. The instant ts2 is detected on the pressure curve by the control unit 4. For this purpose, and according to a particular embodiment, the function P (t) is obtained by interpolation from the pressure measurements. As the pressure P increases linearly at the end of the pre-blowing, the derivative of P (t) is constant therein, so that the control unit 4 may at the instant ts2 set the value of the moment when the derivative of P (t) changes value. In a variant, the function P (t) is derived twice, and the control unit 4 assigns at the instant ts2 the value of the moment when the double derivative of P (t) ceases to be zero. These two techniques provide the same result. The instant ts2 is stored by the control unit 4. Finally, the opening control of the primary distributor 33 (that is to say the communication of the primary orifice 36 of the cylinder 23 with the primary source 34) and, simultaneously, closing the secondary distributor 38 (FIG. that is to say the communication of the secondary orifice 41 with the evacuation 40) is given at a time tBi referred to as "boxing start". Assuming identical distributors 33, 38, AtB is the cumulative response time of each distributor 33 or 38 and the cylinder 23, the displacement of the piston 27 (and thus the bottom 9 of mold) starting at a moment called "actual departure boxing "tB2 such that tB2 = tBi + AtB, which marks the actual start of displacement of the mold bottom 9. The time tB2 is detected on the boxing curve by the control unit 4. For this purpose, the control unit 4 assigns at time tB2 the value of the instant from which the function H (t) (which can be calculated by polynomial interpolation from the position measurements) changes its value, or from which the derivative of H (t) ceases to be zero. The instant tB2 is stored by the control unit 4. [0019] Note also ts3 the moment when the pressure in the container 2 ceases to grow because having reached its maximum (that is to say the blowing pressure), at which the pressure P remains substantially equal for a predetermined duration called bearing blowing, or stabilization period. The instant ts3 is detected on the pressure curve by the control unit 4. For this purpose, the control unit 4 detects for example during the blowing phase the cancellation of the derivative of the function P (t) or the time at which the pressure in the container 2 reaches the blowing pressure, possibly corrected a predetermined value corresponding to the pressure drops that may affect the forming unit 1, and which corresponds to the beginning of the blowing step. The instant ts3 is stored by the control unit 4. We then note tB3 the moment when the bottom 9 of mold reaches its high position, having traveled all its course C. The moment tB3, which marks the end of boxing, is advantageously posterior to the instant ts3, that is, that is to say that the boxing must be completed after the start of the blow-off stage (in other words after the end of the pressure rise of the container 2 due to blowing). The time tB3 is detected on the boxing curve by the control unit 4. For this purpose, the control unit 4 assigns at time tB3 the value of the moment when the derivative of the function H (t) vanishes. The time tB3 is stored by the control unit 4. [0020] As already indicated, and as can be seen in FIG. 4, boxing is initiated before blowing: tB2 <ts2. The response times Ats and AtB respectively affecting the solenoid valve 19 for blowing and the distributors 33, 38 are programmed in the control unit 4, which takes this into account for the opening control of the solenoid valve 19 and the distributors 33, 38 allows to initiate boxing before blowing. However, it has been found that the only inequality tB2 <ts2 is not sufficient to guarantee good container quality (in particular as regards the mechanical performance of the bottom of the container 2). Indeed, it is necessary that the interval Ti between the real starting time tB2 boxing and the instant ts2 actual starting blow (Ti = ts2 - tB2) is substantially constant during the cycles, and equal to a reference value predetermined non-zero, noted Tire. The term "equal" does not mean that Ti and Tire are strictly equal, but that the gap between them is imperceptible, that is to say less than a few percent, typically 5%. In other words, Ti and Tire are decreed equal if: 0.95.T1ref Ti 1 .05.T1ref In what follows, for simplicity, it is agreed that: - Ti = Tire means that 0.95.T1ref Ti 1.05.T1ref; Ti> T'ire means that Ti> 1.05.T1ref; Ti <Tire means that Ti <0.95.T1ref; Ti Tire means that Ti> Tire or Ti <T1 ref. The response times 44, Ats and AtB may experience drifts, which result from frictional wear and mechanical fatigue of the moving parts of the solenoid valves 16, 19 and distributors 33, 38. One can imagine reprogramming the response time regularly. solenoid valves 16, 19 and distributors 33, 38 but a complete shutdown of the machine is necessary to carry out the measurements, which causes the production to be stopped. [0021] This is why it is better to monitor - and correct if necessary - the observed drifts of Ti with respect to Tire. For each forming unit 1, the control unit 4 calculates the interval Ti from the stored values of tB2 and ts: Ti = ts - tB2 and compares Ti with the reference value Tire. This calculation and this comparison can be carried out at each cycle (and more precisely at the end of each cycle, that is to say between the evacuation of a container 2 formed and the loading of a new blank 3). , or periodically (eg every five to ten cycles). When the calculation is carried out periodically, the comparison with the reference value can be made on the basis of an average of values of Ti measured during several successive cycles. As long as Ti Tire, then the control unit 4 shifts the boxing start tBi for the next cycle, so as to reset Ti on Tire. [0022] This adjustment is performed by shifting the box start tBi, on command of the control unit 4 acting on the single distributor 33. It is indeed assumed that the shift of the flow starter ts1 is performed separately by the control unit 4 depending on other parameters (in particular the correct positioning of a peak pressure during the pre-blowing phase). To better explain the correction applied by the control unit 4, the forming cycles are indexed by assigning to a given cycle the whole index N, and to the cycle following the index N + 1, in the manner of the mathematical sequences. [0023] When, for the cycle N (or for a predetermined number of cycles NP to N, where P is a positive whole number less than N), T1 (N) T'ire, the control unit 4 performs for the next cycle N +1 the shift of the boxing start tBi (N + 1) by applying the following rule: - if T1 (N) = then draw tBi (N + 1) = tBi (N), which keeps the starting boxing (and therefore the whole boxing phase), if T1 (N)> Then draw tBi (N + 1) = tBi (N) - (T1 (N) - T1 ref), which advances the starting boxing (and therefore the whole boxing phase), if T1 (N) <then draws tBi (N + 1) = tBi (N) + (T1 (N) - T1 ref), which delays the start of boxing (and therefore the whole boxing phase) ). (In the above, T1 (N) denotes the value of Ti at the N cycle or the Ti average at the NP to N cycles.) Such a cyclic correction limits the risk of Ti drift which, kept substantially constant during the cycles, promotes the uniformity and quality of the containers produced. T2 is also noted the total duration of the boxing, that is to say the interval between the instant tB2 starting real boxing and time tB3 end of boxing: T2 = tB3 - tB2. It has indeed been found that the quality of the containers also depends on the interval T2, which must advantageously be maintained substantially equal to a predetermined reference value T2ref. This is why it is better to monitor - and correct if necessary - the observed drifts of T2 compared to T2ref. As before, the term "equal" does not mean that T2 and T2ref are strictly equal, but that the difference between them is imperceptible, that is to say less than a few percent, typically 5%. In other words, T2 and T2ref are decreed equal if: 0.95.T2ref T2 1.05.T2ref In what follows, for simplicity, it is agreed that: - T2 = T2ref means that 0.95.T2ref T2 1.05.T2ref; T2> T2ref means that T2> 1.05.T2ref; T2 <T2ref means that T2 <0.95.T2ref; T2 T2ref means that T2> T2ref or T2 <T2ref. The interval T2 is a function of the casing stroke C and the boxing speed, that is to say the movement speed of the mold base 9 (and therefore of the piston 27). In production, the stroke C of the mold bottom 9 is fixed, because determined by the choice of the cylinder 23 and by its possible adjustment, which is only performed periodically during the maintenance phases 30 of the forming unit 1. As can be seen in FIG. 4, the boxing speed is not constant during boxing. In fact, the forces opposing the rise of the mold base 9 increase with the rise of the pressure in the blank 3 as soon as it reaches the surface 10 of the bottom 9 of the mold. [0024] Any variation affecting the blowing curve therefore changes the speed of movement of the mold bottom 9, and therefore the value of the interval T2. But the movement speed of the mold bottom 9 can be changed from one cycle N (or cycles NP to N) to the next cycle N + 1, by action on the pressure variator 37 and / or on the speed variator 42 . For each forming unit 1, the control unit 4 calculates the interval T2 from the stored values of tB2 and tB3: T2 = tB3-tB2 and compares T2 with the reference value T2ref. Like Ti, T2 can be corrected at each cycle or periodically. In the latter case, the comparison with the reference value T2ref can be based on an average of the T2 values measured over successive cycles. As T2 T2f, then the control unit 4 modifies the fluid pressure at the pressure variator 37 and / or the fluid flow rate at the speed controller 42, so as to reset T2 on T2ref. More precisely, when, for the cycle N (or for the cycles NP to N), T2 (N) T2ref, the control unit 4 performs for the following cycle N + 1 the modification of the pressure at the level of the variator 37 of FIG. pressure and the flow rate at the drive 37 by applying the following rule: if T2 (N) = T2ref then the flow is maintained, if T2 (N)> T2ref then the flow is increased to increase the boxing speed and thus advance the instant tB3, - if T2 (N) <T2ref then the flow is reduced to reduce the boxing speed and thus delay the time tB3. (In the above, T2 (N) denotes the value of T2 at the N cycle or the T2 average at the NP to N cycles.) Such a cyclic correction limits the risk of T2 drift, the regulation of which favors uniformity. and the quality of the containers produced. As an alternative to the regulation of the interval T2, it is possible, for the same reasons and in the same way, to regulate an interval T3 separating the instant ts3 at which the pressure in the container 2 reaches the value of the blowing pressure and the end of boxing time tB3: T3 = tB3 - ts3. [0025] In this case, it is the interval T3 that it is advantageous to maintain, from a cycle N (or cycles N-P to N) to the next cycle N + 1, equal to a predetermined reference value T3ref. It is then preferable to monitor at each cycle - and correct if necessary - the drifts observed of T3 compared to T3ref. As before, the term "equal" does not mean that T3 and T3ref are strictly equal, but that the difference between them is imperceptible, that is to say less than a few percent, typically 5%. In other words, T3 and T3ref are decreed equal if: 0.95.T3ref T3 1.05.T3ref In what follows, for simplicity, it is agreed that: T3 = T3ref means that 0.95.T3ref T3 1.05.T3ref; T3> T3ref means that T3> 1.05.T3ref; T3 <T3ref means that T3 <0.95.T3ref; T3 T3ref means that T3> T3ref or T3 <T3ref. Like T2, T3 is a function of the boxing C run (fixed in production) and the boxing speed, which can be modified from one N cycle (or NP to N cycles) to the next N + 1 cycle, per action. on the pressure variator 37 and / or on the flow variator 42. But T3 is also a function of the blowing pressure, which determines ts3. For each forming unit 1, the control unit 4 calculates the interval T3 from the stored values of ts3 and tB3: T3 = tB3-ts3 and compares T3 with the reference value T3ref. Like Ti or T2, T3 can be corrected at each cycle or periodically. In the latter case, the comparison with the reference value T3ref can be based on an average of the values of T3 measured during successive cycles. As T3 T3ref, then the control unit 4 modifies the pressure at the level of the drive 37 and / or the fluid flow rate at the drive 42, so as to reset T3 to T3ref. More specifically, when, for the cycle N (or for the average of the cycles NP to N), T3 (N) T3ref, the control unit 4 performs for the next cycle N + 1 the modification of the pressure at the level of the drive 37 and / or the rate at the drive 42 by applying the following rule: if T3 (N) = T3ref then the flow is maintained, If T3 (N)> T3ref then the flow is increased to increase the boxing speed and so to advance the instant tB3, if T3 (N) <T3ref then the flow is restricted to reduce the boxing speed and thus delay the time tB3. (In the above, T3 (N) designates the value of T3 at the N cycle or the average of T3 at the NP to N cycles.) Such a cyclic correction limits the risk of T3 drift, whose regulation favors, like T2 , uniformity and quality of the containers produced. [0026] It has also been found that various other measures, considered separately or in combination, can improve the uniformity and quality of the containers. First, it is possible to detect a failure of the primary distributor 33 and / or the cylinder 23 by the value of the response time AtB. More precisely, as we have seen, the response time AtB is a composite delay equal to the sum of the response time, denoted AtBD, of the distributor 33 and that, noted AtBv, of the jack 23: Atg = AtBD AtBV A With the aid of a pressure sensor mounted in the primary chamber 29 and connected to the control unit 4 which collects the data, it is possible to measure the pressure in the primary chamber 29 and consequently to deduce a value of the response time AtBD, equal to the delay between the start boxing tBi of the instant when the pressure begins to increase in this chamber 29. The control unit 4 can be programmed to compare AtBD with a predetermined threshold value (corresponding to a nominal operation of the primary distributor 33) and, when AtBD is decreed greater than or equal to this threshold value, to conclude a failure of the primary distributor 33 and generate an alert signaling this failure and recommended For example, a stop of the forming unit 1 to replace the primary distributor 33 or perform manual control and / or repair operations thereon. [0027] Similarly, using a motion sensor coupled to the bottom 9 of the mold or the rod 28 (which are integral) and connected to the control unit 4 which collects the data, and in combination with the sensor pressure device mounted in the primary chamber 29, it is possible to detect the movement of the bottom 9 mold and therefore to deduce a value of the response time AtBv, equal to the time between the increase in pressure in the primary chamber 29 and the moment when begins to move the rod 28 (and thus the bottom 9 of mold). The control unit 4 may be programmed to compare AtBv with a predetermined threshold value (corresponding to a normal operation of the jack 23) and, when AtBv is decreed greater than or equal to this threshold value, to conclude that the cylinder 23 has failed. and generate an alert signaling this failure and recommending for example a stop of the forming unit 1 in order to replace the cylinder 23 or perform on it manual control operations and / or repairs. [0028] A failure of the cylinder 23 can also be detected from the position curve of the bottom 9 mold (top in Figure 4) and the blowing curve (bottom in Figure 4). More precisely, it is possible to check the coherence between the position, denoted Hs2, of the mold base 9 at the moment of actual start of blowing, and the duration T2 of the boxing. This consistency can be verified by the control unit 4, which can be programmed to jointly verify that the position Hs2 is between two predetermined values and that the duration T2 is also between two predetermined values and, if these two cumulative conditions (corresponding to a proper operation of the cylinder 23) are not verified, to generate an alert signaling a failure of the cylinder 23 and recommending for example a stop of the forming unit 1 to replace or perform control operations Secondly, it is possible to regulate the value of Hs2 (defined above) by means of the variable speed controller 42, controlled by the control unit 4. At the coordinate point (ts2, Hs2), the boxing curve (at the top of FIG. 4) undergoes a modification of its slope, due to the sudden increase of the pressure in the blank 3, as evidenced by the pressure curve. . [0029] The position of the mold bottom 9 at the instant ts2, that is to say the value of Hs2, must be set relatively accurately because the quality of the container 2 depends on it. Indeed, if the mold bottom 9 is positioned too low at time ts2, there may be a pinching of the material between the bottom 9 of the mold and the opening 8 during blowing. Conversely, if the mold bottom 9 is positioned too high at the instant ts2, the material of the blank 3 may not correctly take the imprint of the inner surface. The position of the mold base 9 at time ts2 depends on the speed of movement of the mold base 9 and can therefore be adjusted by means of the speed variator 42. Therefore, from the measurements collected at the cycle N (or possibly over several cycles NP to N), the control unit 4 checks that Hs2 corresponds to a predetermined reference value and, if this is not the case, pilot the flow variator 42 for starting from the cycle N + 1: decreasing the authorized flow rate so as to slow the piston 27 if the value of Hs2 is greater (with a tolerance) than the reference value; on the other hand, increase the authorized flow rate so as to accelerate the piston 27 if the value of Hs2 is lower (with a tolerance) than the reference value. Finally, it will be noted that it may happen, following the actions of the control unit 4 mentioned above, that the speed variator 42 is set to its minimum (that is to say that it leaves the opening completely open. fluid passage section, in particular to increase the speed of displacement of the piston 27 at constant pressure in the primary chamber 29) or on the contrary to its maximum (that is to say, it closes at most the passage section of the fluid, in particular to reduce the speed of movement of the piston 27 at constant pressure in the primary chamber 29). In both cases, the room for maneuver offered to the control unit 4 to act on the displacement of the mold base 9 and, ultimately, on the boxing curve, are reduced. In order to allow the control unit 4 to find these margins of maneuver, it may be planned to program the control unit 4 to act on the pressure variator 37 so as to: reduce the pressure injected into the primary chamber 29 when the drive 42 reaches its minimum speed; on the contrary, increase the pressure injected into the primary chamber 29 when the variator reaches its maximum flow rate.
权利要求:
Claims (10) [0001] REVENDICATIONS1. Method of manufacturing a container (2) from a plastic blank (3) within a mold (5) having a wall (6) defining a cavity (7) in the cavity of the container (2), and an insert (9) movable relative to the wall (6) between a retracted position and an extended position, this method comprising, after an operation of introducing the blank (3) into the mold: a pre-blowing phase comprising the injection into the blank (3) of a fluid at a pre-blowing pressure; a blowing phase, consecutive to the pre-blowing phase and comprising injecting into the blank (3) a fluid at a blowing pressure greater than the pre-blowing pressure; a boxing phase comprising moving the insert (9) from its retracted position to its deployed position; this method comprising the steps of: measuring in real time the pressure prevailing in the blank (3); memorizing the values of the measured pressure and their respective times of measurement; measuring in real time the position of the insert (9); storing the values of the measured position of the insert (9) and their respective moments of measurement; from the memorized values of the pressure in the blank (3), detecting and storing an instant ts2 marking the actual start of the blowing phase; from the measured position values of the insert (9), detecting and storing an instant tB2 marking the actual beginning of the displacement of the insert (9); calculate the interval, denoted Ti, separating tB2 from tS2; this method being characterized in that it further comprises the steps of: comparing the interval Ti with a predetermined non-zero reference tire value, as long as the interval Ti is decreed different from the reference value Tire, shifting the initiation of the boxing phase. [0002] 2. Method according to claim 1, characterized in that it comprises the operation of, as long as the interval Ti is decreed lower than the reference value Tire, to advance the boxing phase. [0003] 3. Method according to claim 1 or claim 2, characterized in that, the insert (9) being integral with the rod (28) of a cylinder (23) supplied with fluid under pressure via a dispenser (33) with controlled opening, the offset of the initiation of the boxing phase is to shift the opening control of the dispenser (33). [0004] 4. Method according to one of claims 1 to 3, which comprises the operations consisting of: from the measured position values of the insert (9), detecting a time tB3 at which the insert (9) reaches its high position ; calculate the interval, denoted T2, separating tB3 from tB2; comparing the interval T2 with a predetermined non-zero reference reference value T2ref; as long as the interval T2 is decreed different from the value T2ref of reference, modify the speed of displacement of the insert (9) during the boxing phase. [0005] 5. Method according to claim 4, characterized in that, the insert (9) being secured to the rod (28) of a cylinder (23) supplied with fluid under pressure, this method comprises the following operations: measuring the position (Hs2) of the insert (9) at instant ts2 marking the actual start of the blowing phase, - check if the position (Hs2) of the insert (9) is between two predetermined values and if T2 is also between two predetermined values, if these two conditions are not jointly satisfied, generate an alert. [0006] 6. Method according to claim 5, characterized in that, the cylinder (23) being connected to a discharge (40) via a variable speed controller (42), it comprises, if the position (Hs2) of the insert (9) is not between two predetermined values or if T2 is not between two predetermined values, an operation of modifying the fluid flow rate at the flow controller (42). [0007] 7. Method according to one of claims 1 to 3, which comprises the operations consisting of: from the stored values of the pressure in the blank (3), detecting and storing a moment ts3 at which the pressure in the blank ( 3) stops growing during the blowing phase; from the measured position values of the insert (9), detecting a time tB3 at which the insert (9) reaches its high position; calculate the interval, denoted T3, separating ts3 from tB3; comparing the interval T3 with a non-zero predetermined reference value T3ref; as long as the interval T3 is decreed different from the value T3ref of reference, modify the speed of displacement of the insert (9) during the boxing phase. [0008] 8. Method according to claim 7, characterized in that, the insert (9) being integral with the rod (28) of a cylinder (23) supplied with fluid under pressure via a distributor (33) with controlled opening and a pressure variator (37), the modification of the speed of movement of the insert (9) consists in acting on the pressure variator (37) to modify the pressure of the fluid supplying the jack (23). ). [0009] 9. Method according to one of the preceding claims, characterized in that, the insert (9) being secured to the rod (28) of a cylinder (23) supplied with fluid under pressure via a distributor (33) with controlled opening, this method comprises the steps of: measuring a response time of the actuator (23) and / or a response time of the distributor (33) and comparing this response time with a predetermined threshold value, when this response time is greater than the reference value, generate an alert. [0010] 10. Method according to one of the preceding claims, characterized in that, the insert (9) being secured to the rod (28) of a cylinder (23) supplied with fluid under pressure via a distributor Controlled actuator (33) and a pressure variator (37), the actuator (23) being further connected to an evacuation (40) via a flow variator (42), this process includes the operations consisting, if the flow rate at the drive (42) reaches a minimum, respectively a maximum, to control the drive (37) pressure to decrease, respectively increase, the pressure injected into the cylinder (23) .5
类似技术:
公开号 | 公开日 | 专利标题 EP3240668B1|2019-01-02|Method for manufacturing a container including boxing timed with blowing EP2709821B1|2019-09-04|Method for manufacturing containers, including an anticipated boxing operation EP2922682B1|2019-01-09|Method for stretch-blow moulding a container, including measuring the movement of the stretch rod during a boxing operation EP2919963B1|2016-10-26|Method for producing containers, comprising a delayed boxing operation EP2709818B1|2018-08-22|Method for the stretch-blowing of a container, comprising a retraction of the stretch rod during a boxing operation EP2094467B1|2011-08-10|Method and apparatus for producing a vessel from a preform with feedback depending on the expansion end point of the preform FR3019486A1|2015-10-09|MANUFACTURING METHOD AND MOLDING UNIT OF CONTAINERS WITH LARGE BOXING RUN EP2101984B1|2014-02-12|Method for producing a vessel from a preform with feedback depending on the preform development point EP2616228B1|2016-03-23|Method for manufacturing a container from a preform, with feedback depending on a minimum pressure detected EP2097242A2|2009-09-09|Method for producing vessels with feedback depending on the pre-blowing starting point EP2855114B1|2016-08-31|Method for manufacturing a container from a blank, including feedback in accordance with an actual pressure at the end of the pre-blowing step KR102112376B1|2020-05-18|Method and apparatus for injection molding of plastic materials WO2009044067A2|2009-04-09|Process for forming containers, which comprises a step of flushing the internal volume of the container of variable duration over at least one given compensation time FR3079442A1|2019-10-04|PROCESS FOR MANUFACTURING CONTAINERS BY ADJUSTABLE BOXING BASED ON THE BLOWING CURVE FR3027248A1|2016-04-22|MOLDING WITH SEALED JOINT PLANE FOR MANUFACTURING CONTAINERS FR3072321B1|2019-09-27|MOLDING UNIT EQUIPPED WITH A PROPORTIONAL SOLENOID BOXING SYSTEM WO2009103927A2|2009-08-27|Process and device for manufacturing a plastic container by blow moulding WO2014170577A1|2014-10-23|Mould with a movable bottom and horizontal joint plane FR3063926A1|2018-09-21|METHOD FOR AUTOMATICALLY ADJUSTING THE RUNNING OF A STRETCH ROD OF A HOLLOW BODY FORMING DEVICE FR3103729A1|2021-06-04|Device and method for treating hollow bodies. FR2997339A1|2014-05-02|PROCESS FOR BLOWING CONTAINERS WITH A BEARING, AND MACHINE FOR SAID METHOD
同族专利:
公开号 | 公开日 CN107000304A|2017-08-01| CN107000304B|2019-03-12| EP3240668A1|2017-11-08| FR3029133B1|2016-12-30| WO2016083711A1|2016-06-02| US11123914B2|2021-09-21| EP3240668B1|2019-01-02| US20170326780A1|2017-11-16|
引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题 US5122327A|1991-04-18|1992-06-16|Hoover Universal, Inc.|Blow molding method for making a reversely oriented hot fill container| US20090139996A1|2005-08-18|2009-06-04|Sidel Participations|Mold, method and installation for blow-molding thermoplastic containers provided with an integral handle, and container thus produced| US20100204819A1|2006-12-05|2010-08-12|Isabelle Monin|Method for producing a vessel from a preform, with feedback depending on the expansion end point of the preform| US20110298162A1|2008-12-03|2011-12-08|Sidel Participations|Method and device for forming containers with counter-pressure| EP2709821A1|2011-05-19|2014-03-26|Sidel Participations|Method for manufacturing containers, including an anticipated boxing operation| US20140203481A1|2011-05-19|2014-07-24|Sidel Participations|Method for the stretch-blowing of a container, comprising a retraction of the stretch rod during a boxing operation|WO2018114462A1|2016-12-23|2018-06-28|Krones Ag|Method and device for blow moulding containers with a movable bottom part| WO2018114427A1|2016-12-23|2018-06-28|Krones Ag|Method and device having a mobile base part, for blow molding containers| WO2018114439A1|2016-12-23|2018-06-28|Krones Ag|Method and device having a mobile base part, for blow molding containers| WO2018146331A3|2017-02-13|2018-10-04|Krones Ag|Device and method for transforming plastic preforms into plastic bottles with a moveable base| WO2019186007A1|2018-03-28|2019-10-03|Sidel Participations|Method for producing containers, by boxing that can be adjusted depending on the blowing curve|JP2914716B2|1990-05-07|1999-07-05|昭和電工株式会社|Automotive bumper molding method| JP3231491B2|1993-06-10|2001-11-19|日精エー・エス・ビー機械株式会社|Injection stretch blow molding equipment| US5470218A|1993-07-07|1995-11-28|Wheaton Inc.|Graphical interface driven injection blow molding apparatus| FR2919579B1|2007-07-30|2011-06-17|Sidel Participations|CONTAINER COMPRISING A BACKGROUND WITH A DEFORMABLE MEMBRANE.| FR2964902B1|2010-09-16|2012-10-12|Sidel Participations|PROCESS FOR MANUFACTURING A CONTAINER FROM A BLANK, WITH FEEDBACK BASED ON A MINIMUM PRESSURE DETECTOR| EP2463079A1|2010-12-10|2012-06-13|Nestec S.A.|A process for single-step forming and filling of containers| WO2012112474A2|2011-02-15|2012-08-23|Amcor Limited|Reverse stretch rod for machine hygiene and processing| US9044887B2|2011-05-27|2015-06-02|Discma Ag|Method of forming a container| CN102514180B|2012-01-05|2013-11-27|四川省资阳市雅之江塑业有限公司|Adjusting mechanism for blowing device of hollow blow molding machine| FR2998207B1|2012-11-20|2015-01-16|Sidel Participations|METHOD OF STRETCH BLOWING A CONTAINER, COMPRISING A MEASUREMENT OF THE SHIFT OF THE STRETCH ROD DURING A BOXING OPERATION|FR3063926B1|2017-03-17|2019-04-12|Sidel Participations|METHOD FOR AUTOMATICALLY ADJUSTING THE RUNNING OF A STRETCH ROD OF A HOLLOW BODY FORMING DEVICE| DE102017114138A1|2017-06-26|2018-12-27|Krones Ag|Apparatus and method for switching time compensation on the valve block| FR3072321B1|2017-10-16|2019-09-27|Sidel Participations|MOLDING UNIT EQUIPPED WITH A PROPORTIONAL SOLENOID BOXING SYSTEM| CN109895353B|2019-02-19|2021-03-05|戴光平|Blow molding device used for plastic barrel production and convenient to fix and seal|
法律状态:
2015-10-23| PLFP| Fee payment|Year of fee payment: 2 | 2016-06-03| PLSC| Search report ready|Effective date: 20160603 | 2016-10-24| PLFP| Fee payment|Year of fee payment: 3 | 2017-10-20| PLFP| Fee payment|Year of fee payment: 4 | 2018-10-24| PLFP| Fee payment|Year of fee payment: 5 | 2019-10-22| PLFP| Fee payment|Year of fee payment: 6 | 2021-08-06| ST| Notification of lapse|Effective date: 20210705 |
优先权:
[返回顶部]
申请号 | 申请日 | 专利标题 FR1461575A|FR3029133B1|2014-11-27|2014-11-27|PROCESS FOR MANUFACTURING BOXING CONTAINER BASED ON BLOWING|FR1461575A| FR3029133B1|2014-11-27|2014-11-27|PROCESS FOR MANUFACTURING BOXING CONTAINER BASED ON BLOWING| EP15810688.0A| EP3240668B1|2014-11-27|2015-11-23|Method for manufacturing a container including boxing timed with blowing| US15/531,140| US11123914B2|2014-11-27|2015-11-23|Method for manufacturing a container including boxing timed with blowing| CN201580064443.XA| CN107000304B|2014-11-27|2015-11-23|The manufacturing method for container of opposite blowing adjustment impact| PCT/FR2015/053166| WO2016083711A1|2014-11-27|2015-11-23|Method for manufacturing a container including boxing timed with blowing| 相关专利
Sulfonates, polymers, resist compositions and patterning process
Washing machine
Washing machine
Device for fixture finishing and tension adjusting of membrane
Structure for Equipping Band in a Plane Cathode Ray Tube
Process for preparation of 7 alpha-carboxyl 9, 11-epoxy steroids and intermediates useful therein an
国家/地区
|